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Zipper Assembly of Vectorial Rigid‐Rod π‐Stack Architectures with Red and Blue Naphthalenediimides: Toward Supramolecular Cascade n/p‐Heterojunctions
Author(s) -
Sisson Adam L.,
Sakai Naomi,
Banerji Natalie,
Fürstenberg Alexandre,
Vauthey Eric,
Matile Stefan
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200800203
Subject(s) - cascade , stack (abstract data type) , zipper , supramolecular chemistry , heterojunction , optoelectronics , materials science , nanotechnology , crystallography , chemistry , computer science , crystal structure , algorithm , chromatography , programming language
Zipped up: Supramolecular 3D organization on gold with interdigitating intra‐ and interlayer recognition motifs (see picure, black p ‐oligophenyl rods; red, blue naphthalenediimide (NDI) stacks) is designed to access supramolecular cascade n/p‐heterojunctions or the adaptable directionality needed to control fill factors in current–voltage curves.