Simultaneous Copper(I)‐Catalyzed Azide–Alkyne Cycloaddition (CuAAC) and Living Radical Polymerization | Zendy

Geng Jin | Zendy; Lindqvist Josefina | Zendy; Mantovani Giuseppe | Zendy; Haddleton David M. | Zendy

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Simultaneous Copper(I)‐Catalyzed Azide–Alkyne Cycloaddition (CuAAC) and Living Radical Polymerization

Author(s) -

Geng Jin,

Lindqvist Josefina,

Mantovani Giuseppe,

Haddleton David M.

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200800179

Subject(s) - cycloaddition , azide , alkyne , polymerization , chemistry , catalysis , copper , solvent , click chemistry , polymer chemistry , combinatorial chemistry , photochemistry , polymer , organic chemistry

All in one : CuBr/iminopyridine systems can catalyze simultaneously both copper(I)‐catalyzed azide–alkyne cycloaddition (CuAAC, “click”) and living radical polymerization (LRP) processes (see scheme). The relative rate of the two processes can be tailored by a judicious choice of the reaction conditions (solvent, temperature, [CuBr] 0 ) leading to the development of a potentially very efficient synthetic route to well‐defined functional polymers.

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