Synthesis of a Paramagnetic Polymer by Ring‐Opening Polymerization of a Strained [1]Vanadoarenophane | Zendy

Braunschweig Holger | Zendy; Adams Christopher J. | Zendy; Kupfer Thomas | Zendy; Manners Ian | Zendy; Richardson Robert M. | Zendy; Whittell George R. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Synthesis of a Paramagnetic Polymer by Ring‐Opening Polymerization of a Strained [1]Vanadoarenophane

Author(s) -

Braunschweig Holger,

Adams Christopher J.,

Kupfer Thomas,

Manners Ian,

Richardson Robert M.,

Whittell George R.

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200800081

Subject(s) - cleavage (geology) , platinum , bond cleavage , ring (chemistry) , boron , polymerization , stoichiometry , polymer , salt (chemistry) , chemistry , derivative (finance) , polymer chemistry , materials science , catalysis , organic chemistry , composite material , fracture (geology) , financial economics , economics

Salt‐elimination reactions led to the formation of highly strained [1]bora‐ and [1]silavanadoarenophanes, which undergo different types of ring‐opening reactions with low‐valent platinum complexes. Whereas the boron‐bridged derivative opened stoichiometrically by cleavage of the VC arene bond, the [1]silavanadoarenophane reacted at the SiC ipso bond to afford a polymer containing spin‐active metal centers in the main chain (see scheme).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research