Fourteen‐Electron Bis(dialkylsilylene)palladium and Twelve‐Electron Bis(dialkylsilyl)palladium Complexes | Zendy

Watanabe Chieko | Zendy; Iwamoto Takeaki | Zendy; Kabuto Chizuko | Zendy; Kira Mitsuo | Zendy

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Fourteen‐Electron Bis(dialkylsilylene)palladium and Twelve‐Electron Bis(dialkylsilyl)palladium Complexes

Author(s) -

Watanabe Chieko,

Iwamoto Takeaki,

Kabuto Chizuko,

Kira Mitsuo

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200705954

Subject(s) - palladium , electron , silylene , silylation , magenta , chemistry , crystallography , materials science , physics , silicon , organic chemistry , nuclear physics , catalysis , inkwell , composite material

Hydrogens make a difference : The first 14‐electron bis(silylene)palladium ( A ) and 12‐electron bis(silyl)palladium complexes ( B ) are synthesized from a stable dialkylsilylene (see picture; gold: Pd; dark blue: Si; light blue: C; magenta: H). The remarkable difference between the L‐M‐L angles of these two complexes is rationalized by applying the Walsh diagram.

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