A Pincer‐Type Anionic Platinum(0) Complex | Zendy

Schwartsburd Leonid | Zendy; Cohen Revital | Zendy; Konstantinovski Leonid | Zendy; Milstein David | Zendy

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A Pincer‐Type Anionic Platinum(0) Complex

Author(s) -

Schwartsburd Leonid,

Cohen Revital,

Konstantinovski Leonid,

Milstein David

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200705927

Subject(s) - pincer movement , protonation , platinum , reactivity (psychology) , hydride , chemistry , ion , electron transfer , medicinal chemistry , combinatorial chemistry , photochemistry , catalysis , metal , organic chemistry , medicine , alternative medicine , pathology

Holding a Pt 0 anion in a pincer: Reduction of the pincer‐type Pt II complex 1 results in the formation of the thermally stable anionic Pt 0 complex 2 . This complex adopts a T‐shaped structure and exhibits diverse reactivity, including efficient electron‐transfer processes in which 2 is re‐oxidized quantitatively to Pt II . Protonation of 2 with water gives a Pt II hydride complex, and CF activation under mild conditions leads to 3 (see scheme).

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