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Aerobic Oxidative Kinetic Resolution of Racemic Secondary Alcohols with Chiral Bifunctional Amido Complexes
Author(s) -
Arita Sachiko,
Koike Takashi,
Kayaki Yoshihito,
Ikariya Takao
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200705875
Subject(s) - kinetic resolution , bifunctional , chemistry , oxidative phosphorylation , kinetic energy , stereochemistry , organic chemistry , enantioselective synthesis , catalysis , biochemistry , physics , quantum mechanics
Up for air : The aerobic oxidative kinetic resolution of racemic secondary alcohols with chiral bifunctional Ir, Rh, and Ru catalysts proceeds smoothly under mild conditions to provide chiral alcohols with up to 99 % ee , and O 2 serves as an excellent hydrogen acceptor.
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