Charge Compensation in Solid Solutions | Zendy

Schmidt Moritz | Zendy; Stumpf Thorsten | Zendy; Marques Fernandes Maria | Zendy; Walther Clemens | Zendy; Fanghänel Thomas | Zendy

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Charge Compensation in Solid Solutions

Author(s) -

Schmidt Moritz,

Stumpf Thorsten,

Marques Fernandes Maria,

Walther Clemens,

Fanghänel Thomas

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200705827

Subject(s) - compensation (psychology) , charge (physics) , lanthanide , ion , solid solution , calcite , materials science , chemical physics , chemistry , inorganic chemistry , mineralogy , physics , metallurgy , psychology , organic chemistry , quantum mechanics , psychoanalysis

Compensating differences : The formation of solid solutions is still not fully understood. A basic principle requiring clarification is the charge compensation mechanism upon incorporation of differently charged ions. Spectroscopic measurements show how coupled substitution of Na + with Eu 3+ /Cm 3+ can provide charge compensation when incorporating trivalent lanthanides into calcite on the Ca 2+ site.

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