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Charge Compensation in Solid Solutions
Author(s) -
Schmidt Moritz,
Stumpf Thorsten,
Marques Fernandes Maria,
Walther Clemens,
Fanghänel Thomas
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200705827
Subject(s) - compensation (psychology) , charge (physics) , lanthanide , ion , solid solution , calcite , materials science , chemical physics , chemistry , inorganic chemistry , mineralogy , physics , metallurgy , psychology , organic chemistry , quantum mechanics , psychoanalysis
Compensating differences : The formation of solid solutions is still not fully understood. A basic principle requiring clarification is the charge compensation mechanism upon incorporation of differently charged ions. Spectroscopic measurements show how coupled substitution of Na + with Eu 3+ /Cm 3+ can provide charge compensation when incorporating trivalent lanthanides into calcite on the Ca 2+ site.