Kinetic Gate‐Opening Process in a Flexible Porous Coordination Polymer | Zendy

Tanaka Daisuke | Zendy; Nakagawa Keiji | Zendy; Higuchi Masakazu | Zendy; Horike Satoshi | Zendy; Kubota Yoshiki | Zendy; Kobayashi Tatsuo C. | Zendy; Takata Masaki | Zendy; Kitagawa Susumu | Zendy

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Kinetic Gate‐Opening Process in a Flexible Porous Coordination Polymer

Author(s) -

Tanaka Daisuke,

Nakagawa Keiji,

Higuchi Masakazu,

Horike Satoshi,

Kubota Yoshiki,

Kobayashi Tatsuo C.,

Takata Masaki,

Kitagawa Susumu

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200705822

Subject(s) - adsorption , process (computing) , kinetic energy , polymer , porosity , molecule , porous medium , transformation (genetics) , materials science , chemistry , computer science , physics , organic chemistry , quantum mechanics , operating system , biochemistry , gene

Open the gate! A porous coordination polymer shows abrupt changes in its adsorption isotherm with guest‐dependent gate‐opening pressure (see picture). Kinetic analysis reveals that adsorption with structure transformation follows a gate‐opening model, in which adsorption proceeds through the formation of an intermediate by a gate‐opening process. This process provides a significant difference in onset pressure between similar gas molecules.

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