Dibenzo[ c , g ]fluorenyliron: An Organometallic Relative of Pentahelicene | Zendy

Pammer Frank | Zendy; Sun Yu | Zendy; Pagels Markus | Zendy; Weismann Daniel | Zendy; Sitzmann Helmut | Zendy; Thiel Werner R. | Zendy

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Dibenzo[ c , g ]fluorenyliron: An Organometallic Relative of Pentahelicene

Author(s) -

Pammer Frank,

Sun Yu,

Pagels Markus,

Weismann Daniel,

Sitzmann Helmut,

Thiel Werner R.

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200705743

Subject(s) - organometallic chemistry , ligand (biochemistry) , group 2 organometallic chemistry , chemistry , stereochemistry , center (category theory) , combinatorial chemistry , crystallography , catalysis , computational chemistry , molecule , organic chemistry , receptor , biochemistry

Close relatives! The Pd‐catalyzed hydrogenation of the “isolated” CC double bonds of dibenzo[ c , g ]fluorenide coordinated to an Fe II center confirms that the electronic structure of this ligand in organometallic compounds is related to that of cyclopentadienide. The resulting 3,4,3′,4′‐tetrahydrodibenzo[ c , g ]fluorenide is a new chiral cyclopentadienide ligand (see picture for the molecular structure of the Fe complex).

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