A Nitrido‐Centered Uranium Azido Cluster Obtained from a Uranium Azide | Zendy

Nocton Grégory | Zendy; Pécaut Jacques | Zendy; Mazzanti Marinella | Zendy

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A Nitrido‐Centered Uranium Azido Cluster Obtained from a Uranium Azide

Author(s) -

Nocton Grégory,

Pécaut Jacques,

Mazzanti Marinella

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200705742

Subject(s) - uranium , azide , actinide , orange (colour) , chemistry , cluster (spacecraft) , ligand (biochemistry) , combinatorial chemistry , nuclear chemistry , computer science , operating system , organic chemistry , materials science , biochemistry , metallurgy , receptor , food science

Caught in the actinide : A tetranuclear azido/nitrido uranium anion containing eight end‐on bridging azido ligands and a μ 4 interstitial nitrido ligand has been isolated and structurally characterized (see 1D chain; U green, Cs orange, I magenta, N blue, C white). A new two‐step procedure has been developed to promote the cluster assembly by oxidation of [UI 3 (thf) 4 ] with a preformed uranium heptaazido complex.

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