Strained Metallocenophanes with Late Transition Metals in the Bridge: Syntheses and Structures of Nickel‐ and Platinum‐Bridged [1]Ferrocenophanes | Zendy

Whittell George R. | Zendy; Partridge Benjamin M. | Zendy; Presly Oliver C. | Zendy; Adams Christopher J. | Zendy; Manners Ian | Zendy

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Strained Metallocenophanes with Late Transition Metals in the Bridge: Syntheses and Structures of Nickel‐ and Platinum‐Bridged [1]Ferrocenophanes

Author(s) -

Whittell George R.,

Partridge Benjamin M.,

Presly Oliver C.,

Adams Christopher J.,

Manners Ian

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200705672

Subject(s) - platinum , nickel , bridge (graph theory) , transition metal , transition (genetics) , chemistry , materials science , crystallography , metallurgy , organic chemistry , catalysis , biochemistry , biology , gene , anatomy

Late and unexpected : The first strained metallocenophanes with a single late transition‐metal atom in the bridge have been prepared (see scheme). The nickel‐ and platinum‐bridged complexes are the first [1]ferrocenophanes where the bridging atom has a distorted square‐planar geometry, and the compounds are substantially more tilted and electron‐rich than early transition‐metal analogues.

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