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Exploring Crystal Morphology of Nanoporous Hosts from Time‐Dependent Guest Profiles
Author(s) -
Tzoulaki Despina,
Heinke Lars,
Schmidt Wolfgang,
Wilczok Ursula,
Kärger Jörg
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200705597
Subject(s) - nanoporous , zeolite , diffusion , crystal (programming language) , morphology (biology) , materials science , crystallography , molecule , chemical physics , chemical engineering , nanotechnology , chemistry , geology , thermodynamics , physics , organic chemistry , paleontology , computer science , engineering , programming language , catalysis
The persistence of resistance : In the zeolite silicalite‐1, the influence of transport barrier on the surface and between crystal segments, are negligibly small in comparison to the transport resistance of the intracrystalline pore system. Diffusion experiments are conducted with these zeolite crystals and intracrystalline diffusion coefficients of guest molecules determined.