Transition‐Metal Complexes with Singly Reduced 1,2‐Diketone Radical Ligands | Zendy

Spikes Geoffrey H. | Zendy; Bill Eckhard | Zendy; Weyhermüller Thomas | Zendy; Wieghardt Karl | Zendy

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Transition‐Metal Complexes with Singly Reduced 1,2‐Diketone Radical Ligands

Author(s) -

Spikes Geoffrey H.,

Bill Eckhard,

Weyhermüller Thomas,

Wieghardt Karl

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200705410

Subject(s) - chemistry , tris , ligand (biochemistry) , transition metal , organometallic chemistry , nickel , metal , stereochemistry , medicinal chemistry , polymer chemistry , organic chemistry , catalysis , biochemistry , receptor

Radically single : Two complexes featuring a singly reduced 1,2‐diketonate(1−) π‐radical ligand, namely the tris(ligand) radical iron complex [Fe III L . 3 ] ( S =1) and the low‐valent organometallic nickel complex [Ni I L . (cod)] ( S =0; cod=cycloocta‐1,5‐diene), are isolated and characterized (see picture).

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