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Directed 1D Assembly of a Ring‐Shaped Inorganic Nanocluster Templated by an Organic Rigid‐Rod Molecule: An Inorganic/Organic Polypseudorotaxane
Author(s) -
Alam Md. Akhtarul,
Kim YeongSang,
Ogawa Saho,
Tsuda Akihiko,
Ishii Noriyuki,
Aida Takuzo
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200705308
Subject(s) - molecule , ring (chemistry) , ammonium , organic molecules , crystallography , chemistry , ion , cluster (spacecraft) , nanostructure , materials science , nanotechnology , organic chemistry , computer science , programming language
Facing up to matters : Template‐assisted cofacial assembly of a ring‐shaped polyoxomolybdate cluster (MC) by an oligomeric p ‐phenylenebutadiynylene rigid rod molecule bearing ammonium ion pendant groups (PB n ) allowed for the formation of an inorganic/organic one‐dimensional (1D) nanoobject. Studies indicate that the 1D object most likely has a polypseudorotaxane structure (see picture), in which multiple MC rings are threaded by the PB n rod.