Directed 1D Assembly of a Ring‐Shaped Inorganic Nanocluster Templated by an Organic Rigid‐Rod Molecule: An Inorganic/Organic Polypseudorotaxane | Zendy

Alam Md. Akhtarul | Zendy; Kim YeongSang | Zendy; Ogawa Saho | Zendy; Tsuda Akihiko | Zendy; Ishii Noriyuki | Zendy; Aida Takuzo | Zendy

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Directed 1D Assembly of a Ring‐Shaped Inorganic Nanocluster Templated by an Organic Rigid‐Rod Molecule: An Inorganic/Organic Polypseudorotaxane

Author(s) -

Alam Md. Akhtarul,

Kim YeongSang,

Ogawa Saho,

Tsuda Akihiko,

Ishii Noriyuki,

Aida Takuzo

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200705308

Subject(s) - molecule , ring (chemistry) , ammonium , organic molecules , crystallography , chemistry , ion , cluster (spacecraft) , nanostructure , materials science , nanotechnology , organic chemistry , computer science , programming language

Facing up to matters : Template‐assisted cofacial assembly of a ring‐shaped polyoxomolybdate cluster (MC) by an oligomeric p ‐phenylenebutadiynylene rigid rod molecule bearing ammonium ion pendant groups (PB n ) allowed for the formation of an inorganic/organic one‐dimensional (1D) nanoobject. Studies indicate that the 1D object most likely has a polypseudorotaxane structure (see picture), in which multiple MC rings are threaded by the PB n rod.

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