Ru‐Catalyzed Tandem Cross‐Metathesis/Intramolecular‐Hydroarylation Sequence | Zendy

Chen JiaRong | Zendy; Li ChangFeng | Zendy; An XiaoLei | Zendy; Zhang JiJi | Zendy; Zhu XiaoYu | Zendy; Xiao WenJing | Zendy

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Ru‐Catalyzed Tandem Cross‐Metathesis/Intramolecular‐Hydroarylation Sequence

Author(s) -

Chen JiaRong,

Li ChangFeng,

An XiaoLei,

Zhang JiJi,

Zhu XiaoYu,

Xiao WenJing

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200705194

Subject(s) - tandem , intramolecular force , metathesis , ruthenium , catalysis , sequence (biology) , chemistry , combinatorial chemistry , indole test , salt metathesis reaction , stereochemistry , organic chemistry , materials science , polymerization , biochemistry , composite material , polymer

Sometimes it only takes one to tango : A novel ruthenium‐catalyzed tandem cross‐metathesis/intramolecular‐hydroarylation reaction of alkenyl indoles has been developed which relies on a single catalyst for the tandem sequence and provides an efficient synthesis of fused polycyclic indole compounds with good to excellent overall yields (see scheme; Ts=4‐toluenesulfonyl, DCE=1,2‐dichloroethane, Mes=2,4,6‐Me 3 C 6 H 2 ).

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