Metallaboratranes Derived from a Triphosphanyl–Borane: Intrinsic  C  3  Symmetry Supported by a Z‐Type Ligand | Zendy

Bontemps Sébastien | Zendy; Bouhadir Ghenwa | Zendy; Gu Weixing | Zendy; Mercy Maxime | Zendy; Chen ChunHsing | Zendy; Foxman Bruce M. | Zendy; Maron Laurent | Zendy; Ozerov Oleg V. | Zendy; Bourissou Didier | Zendy

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Metallaboratranes Derived from a Triphosphanyl–Borane: Intrinsic C 3 Symmetry Supported by a Z‐Type Ligand

Author(s) -

Bontemps Sébastien,

Bouhadir Ghenwa,

Gu Weixing,

Mercy Maxime,

Chen ChunHsing,

Foxman Bruce M.,

Maron Laurent,

Ozerov Oleg V.,

Bourissou Didier

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200705024

Subject(s) - borane , ligand (biochemistry) , symmetry (geometry) , envelope (radar) , crystallography , chemistry , solid state , type (biology) , physics , stereochemistry , computer science , geometry , mathematics , catalysis , biology , organic chemistry , telecommunications , biochemistry , radar , receptor , ecology

Symmetry from within : Coordination of a triphosphanyl–borane ligand to gold(I) and platinum(0) affords metallaboratranes exhibiting C 3 symmetry both in solution and in the solid state. Such a helical geometry is supported by axial M→B dative interactions and results from the envelope conformations of the PCCBM metallacycles.

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