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Aerobic Oxidation of Primary Amines to Oximes Catalyzed by DPPH and WO 3 /Al 2 O 3
Author(s) -
Suzuki Ken,
Watanabe Tomonari,
Murahashi ShunIchi
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200705002
Subject(s) - primary (astronomy) , catalysis , dpph , chemistry , organic chemistry , physics , antioxidant , astronomy
Catalytic teamwork : Aerobic oxidation of primary amines to the corresponding oximes proceeds highly efficiently in the presence of the catalysts 1,1‐diphenyl‐2‐picrylhydrazyl (DPPH) and WO 3 /Al 2 O 3 under mild conditions (see scheme). This new method is both selective and environmentally benign.