Product Selection through Photon Flux: Laser‐Specific Lactone Synthesis | Zendy

Roscini Claudio | Zendy; Davies David M. E. | Zendy; Berry Malcolm | Zendy; OrrEwing Andrew J. | Zendy; BookerMilburn Kevin I. | Zendy

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Product Selection through Photon Flux: Laser‐Specific Lactone Synthesis

Author(s) -

Roscini Claudio,

Davies David M. E.,

Berry Malcolm,

OrrEwing Andrew J.,

BookerMilburn Kevin I.

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200704816

Subject(s) - laser , chemistry , flux (metallurgy) , fragmentation (computing) , lactone , photon , irradiation , photochemistry , selectivity , photon flux , wavelength , optoelectronics , materials science , optics , physics , stereochemistry , organic chemistry , nuclear physics , catalysis , computer science , operating system

Lasers flux their muscles: The Norrish type I and type II reactions of 1,3‐indandiones can be controlled by judicious choice of light source. Selectivity depends on photon flux, not wavelength. Laser irradiation lead to lactones (type I); conventional lamp irradiation gives diketones by fragmentation (type II, see scheme).

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