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A Selective Instant Synthesis of a Coordination Network and Its Ab Initio Powder Structure Determination
Author(s) -
Kawano Masaki,
Haneda Tsuyoshi,
Hashizume Daisuke,
Izumi Fujio,
Fujita Makoto
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200704809
Subject(s) - ab initio , materials science , crystallization , powder diffraction , synchrotron , crystallography , diffraction , network structure , porosity , ab initio quantum chemistry methods , coordination number , crystal structure , instant , yield (engineering) , chemical engineering , molecule , chemistry , optics , organic chemistry , computer science , metallurgy , composite material , physics , ion , food science , engineering , machine learning
Fast powders and slow crystals : A uniform powder sample of a flexible porous coordination network is prepared in high yield by kinetically controlled synthesis and its crystal structure solved by synchrotron ab initio powder X‐ray diffraction (see picture). Crystals of a totally different porous network with larger channels for guest encapsulation are also obtained by thermodynamic control in a slow crystallization process.