A Route to Microporous Materials through Oxidative Pillaring of Micas | Zendy

Baumgartner Alexander | Zendy; Sattler Katrin | Zendy; Thun Jürgen | Zendy; Breu Josef | Zendy

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A Route to Microporous Materials through Oxidative Pillaring of Micas

Author(s) -

Baumgartner Alexander,

Sattler Katrin,

Thun Jürgen,

Breu Josef

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200704790

Subject(s) - microporous material , intercalation (chemistry) , pillar , reactivity (psychology) , oxidative phosphorylation , chemical engineering , ion exchange , content (measure theory) , materials science , volume (thermodynamics) , chemistry , nanotechnology , mineralogy , inorganic chemistry , organic chemistry , physics , mathematics , thermodynamics , engineering , ion , medicine , mathematical analysis , biochemistry , alternative medicine , structural engineering , pathology

Oxidative pillaring : The intercalation of a molecular pillar (Me 2 DABCO 2+ ) into synthetic Cs‐tainiolite, which shows sufficient intracrystalline reactivity by an oxidative cation‐exchange mechanism, yields a material with microporosity that resembles zeolites in both narrow pore size distribution and total pore volume. Owing to the high structural Fe content, this pillared clay provides a size‐selective, shape‐selective, and electronically conducting framework.

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