Premium
A Route to Microporous Materials through Oxidative Pillaring of Micas
Author(s) -
Baumgartner Alexander,
Sattler Katrin,
Thun Jürgen,
Breu Josef
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200704790
Subject(s) - microporous material , intercalation (chemistry) , pillar , reactivity (psychology) , oxidative phosphorylation , chemical engineering , ion exchange , content (measure theory) , materials science , volume (thermodynamics) , chemistry , nanotechnology , mineralogy , inorganic chemistry , organic chemistry , physics , mathematics , thermodynamics , engineering , ion , medicine , mathematical analysis , biochemistry , alternative medicine , structural engineering , pathology
Oxidative pillaring : The intercalation of a molecular pillar (Me 2 DABCO 2+ ) into synthetic Cs‐tainiolite, which shows sufficient intracrystalline reactivity by an oxidative cation‐exchange mechanism, yields a material with microporosity that resembles zeolites in both narrow pore size distribution and total pore volume. Owing to the high structural Fe content, this pillared clay provides a size‐selective, shape‐selective, and electronically conducting framework.