Strongly Oxidizing and Reducing Functions Combined in a Single Compound: An Alkyl Gallium Peroxide Possessing a Nine‐Membered (GaR) 3 (O 2 ) 3  Heterocycle | Zendy

Uhl Werner | Zendy; Reza Halvagar Mohammad | Zendy

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Strongly Oxidizing and Reducing Functions Combined in a Single Compound: An Alkyl Gallium Peroxide Possessing a Nine‐Membered (GaR) 3 (O 2 ) 3 Heterocycle

Author(s) -

Uhl Werner,

Reza Halvagar Mohammad

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200704739

Subject(s) - oxidizing agent , alkyl , gallium , intramolecular force , chemistry , peroxide , redox , medicinal chemistry , group (periodic table) , stereochemistry , polymer chemistry , organic chemistry

Organoelement peroxides of the heavier Group 13 elements form a class of extraordinarily reactive compounds, which decompose spontaneously by intramolecular redox processes as a result of the close contact of oxidizing peroxo groups and reducing EC bonds. The synthesis of a unique compound is presented, in which three peroxo ligands bridge three alkyl gallium groups by the formation of a nine‐membered heterocycle (see structural formula).

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