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Novel Reactivity of Side‐On (Disulfido)dicopper Complexes Supported by Bi‐ and Tridentate Nitrogen Donors: Impact of Axial Coordination
Author(s) -
BarNahum Itsik,
York John T.,
Young Victor G.,
Tolman William B.
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200704690
Subject(s) - reactivity (psychology) , redox , sulfur , ligand (biochemistry) , nitrogen , copper , chemistry , combinatorial chemistry , stereochemistry , crystallography , inorganic chemistry , organic chemistry , biochemistry , medicine , alternative medicine , receptor , pathology
What a difference a ligand makes : A comparison of the reactivity of the two complexes shown (Cu green, S yellow, N blue, O red, F pink, C gray) has revealed new redox processes previously unseen for copper–sulfur complexes. Furthermore, intriguing supporting‐ligand effects on the properties of (disulfido)dicopper cores are uncovered.