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Coordination Copolymerization of Polar Vinyl Monomers H 2 CCHX
Author(s) -
Berkefeld Andreas,
Mecking Stefan
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200704642
Subject(s) - copolymer , acrylonitrile , vinyl acetate , monomer , polymer chemistry , methyl acrylate , alkyl , polar , vinyl polymer , chemistry , acrylate , polymer , organic chemistry , physics , astronomy
Rising to the challenge : Neutral phosphinosulfonate Pd II complexes were recently demonstrated to be versatile catalysts even for the challenging insertion copolymerization of polar functionalized vinyl comonomers H 2 CCHX, such as acrylonitrile, vinyl acetate, and alkyl vinyl ethers (see scheme, MA=methyl acrylate).
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