[{2,6‐(Me 2 NCH 2 ) 2 C 6 H 3 }Sn] 2 : An Intramolecularly Coordinated Diorganodistannyne | Zendy

Jambor Roman | Zendy; Kašná Blanka | Zendy; Kirschner Karl N. | Zendy; Schürmann Markus | Zendy; Jurkschat Klaus | Zendy

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[{2,6‐(Me 2 NCH 2 ) 2 C 6 H 3 }Sn] 2 : An Intramolecularly Coordinated Diorganodistannyne

Author(s) -

Jambor Roman,

Kašná Blanka,

Kirschner Karl N.,

Schürmann Markus,

Jurkschat Klaus

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200704635

Subject(s) - intramolecular force , steric effects , characterization (materials science) , tin , chemistry , crystallography , bond length , content (measure theory) , stereochemistry , nanotechnology , crystal structure , materials science , mathematics , organic chemistry , mathematical analysis

Not only steric protection by bulky substituents but also intramolecular N→Sn coordination makes possible the isolation and characterization of dimeric organotin(I) compounds such as [{2,6‐(Me 2 NCH 2 ) 2 C 6 H 3 }Sn] 2 (see structure), which according to a crystallographic study exhibits a SnSn bond length of 2.9712(12) Å.

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