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One‐Step Synthesis and Exploratory Chemistry of [5]Dendralene
Author(s) -
Bojase Gomotsang,
Payne Alan D.,
Willis Anthony C.,
Sherburn Michael S.
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200704470
Subject(s) - domino , simple (philosophy) , computer science , chemistry , atom (system on chip) , scheme (mathematics) , combinatorial chemistry , organic chemistry , mathematics , philosophy , epistemology , parallel computing , catalysis , mathematical analysis
Complex polycycles made simple : A practical synthesis of the simplest cross‐conjugated pentaene, [5]dendralene, is reported. The hydrocarbon undergoes controllable and atom‐efficient domino sequences (see scheme) to generate complex polycyclic frameworks in an operationally simple manner.