Single‐Molecule Magnets with Mesomorphic Lamellar Ordering | Zendy

Terazzi Emmanuel | Zendy; Bourgogne Cyril | Zendy; Welter Richard | Zendy; Gallani JeanLouis | Zendy; Guillon Daniel | Zendy; Rogez Guillaume | Zendy; Donnio Bertrand | Zendy

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Single‐Molecule Magnets with Mesomorphic Lamellar Ordering

Author(s) -

Terazzi Emmanuel,

Bourgogne Cyril,

Welter Richard,

Gallani JeanLouis,

Guillon Daniel,

Rogez Guillaume,

Donnio Bertrand

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200704460

Subject(s) - lamellar structure , layering , magnet , materials science , molecule , crystallography , cluster (spacecraft) , liquid crystal , chemical physics , chemistry , organic chemistry , physics , botany , optoelectronics , quantum mechanics , computer science , programming language , biology

Layering up : The single‐molecule magnets (SMMs) [Mn 12 O 12 (O 2 CR) 16 (H 2 O) 4 ] have been shown to exhibit liquid‐crystalline phases. The mesophases can be smectic or cubic depending on the surface functionality imparted by the R group. A local squarelike arrangement of the cluster cores is observed within the smectic layers. This result is a first step towards the self‐assembly of SMMs on surfaces by a bottom‐up approach.

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