A Submicrometer Wire‐to‐Wheel Metamorphism of Hybrid Tridentate Cyclometalated Platinum(II) Complexes | Zendy

Lu Wei | Zendy; Chui Stephen SinYin | Zendy; Ng KwanMing | Zendy; Che ChiMing | Zendy

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A Submicrometer Wire‐to‐Wheel Metamorphism of Hybrid Tridentate Cyclometalated Platinum(II) Complexes

Author(s) -

Lu Wei,

Chui Stephen SinYin,

Ng KwanMing,

Che ChiMing

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200704450

Subject(s) - platinum , acetonitrile , ligand (biochemistry) , aqueous solution , chemistry , combinatorial chemistry , materials science , nanotechnology , polymer chemistry , stereochemistry , crystallography , organic chemistry , catalysis , receptor , biochemistry

Wheely springy wires : Freestanding and crystalline submicrometer wires, springs, and wheels are grown in aqueous acetonitrile dispersions starting from the organoplatinum(II) complexes 1 and 2 (PF 6 ). The growth mechanism is proposed to involve ligand‐substitution reactions and electrostatic and Pt II ⋅⋅⋅Pt II interactions.

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