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Synthesis, Characterization, and Catalytic Activity of a Well‐Defined Rhodium Siloxide Complex Immobilized on Silica
Author(s) -
Marciniec Bogdan,
Szubert Karol,
Potrzebowski Marek J.,
Kownacki Ireneusz,
Łȩszczak Kinga
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200704362
Subject(s) - hydrosilylation , rhodium , fumed silica , chemistry , catalysis , characterization (materials science) , chemical engineering , polymer chemistry , organic chemistry , nanotechnology , materials science , engineering
Rhodium siloxide surface complex 2 , which was obtained directly by reaction of molecular precursor 1 with aerosil silica and characterized inter alia by solid‐state NMR spectroscopy, is a highly active and stable catalyst for hydrosilylation reactions.