Premium
Structurally Defined Reactions of Sodium TMP–Zincate with Nitrile Compounds: Synthesis of a Salt‐Like Sodium Sodiumdizincate and Other Unexpected Ion‐Pair Products
Author(s) -
Clegg William,
Dale Sophie H.,
Hevia Eva,
Hogg Lorna M.,
Honeyman Gordon W.,
Mulvey Robert E.,
O'Hara Charles T.,
Russo Luca
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200704341
Subject(s) - zincate , nitrile , chemistry , salt (chemistry) , sodium , ion , sodium salt , polymer chemistry , combinatorial chemistry , organic chemistry , inorganic chemistry , zinc
Zany zincation : Seemingly simple zincation reactions of aromatic or aliphatic nitriles are in reality highly complicated affairs involving separated ion pairs (see X‐ray structure; yellow Na, blue N, green Zn; left cation, right anion) or joined ion pairs. The results also show that the free zincate anions can engage in complicated dismutation processes.