Octa‐, Deca‐, Trideca‐, and Tetradecanuclear Heterometallic Cyclic Chromium–Copper Cages | Zendy

Engelhardt Larry P. | Zendy; Muryn Christopher A. | Zendy; Pritchard Robin G. | Zendy; Timco Grigore A. | Zendy; Tuna Floriana | Zendy; Winpenny Richard E. P. | Zendy

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Octa‐, Deca‐, Trideca‐, and Tetradecanuclear Heterometallic Cyclic Chromium–Copper Cages

Author(s) -

Engelhardt Larry P.,

Muryn Christopher A.,

Pritchard Robin G.,

Timco Grigore A.,

Tuna Floriana,

Winpenny Richard E. P.

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200704132

Subject(s) - chromium , ring (chemistry) , copper , amine gas treating , orange (colour) , deca , chemistry , metal , crystallography , polymer chemistry , medicinal chemistry , organic chemistry , food science

Ring around the amine : Reactions which give heterometallic Cr x Cu y rings can be controlled through choice of reaction times, and the mixed products can be separated and crystallized. These new compounds include Cr 7 Cu, Cr 8 Cu 2 , Cr 12 Cu 2 , and Cr 11 Cu 2 rings (see structure; Cu orange, Cr green, F yellow, O red, N blue, C black). The last compound is the largest ring known with an odd number of metal atoms.

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