Nickel/BPh 3 ‐Catalyzed Alkynylcyanation of Alkynes and 1,2‐Dienes: An Efficient Route to Highly Functionalized Conjugated Enynes | Zendy

Nakao Yoshiaki | Zendy; Hirata Yasuhiro | Zendy; Tanaka Masaaki | Zendy; Hiyama Tamejiro | Zendy

Premium

Nickel/BPh 3 ‐Catalyzed Alkynylcyanation of Alkynes and 1,2‐Dienes: An Efficient Route to Highly Functionalized Conjugated Enynes

Author(s) -

Nakao Yoshiaki,

Hirata Yasuhiro,

Tanaka Masaaki,

Hiyama Tamejiro

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200704095

Subject(s) - catalysis , conjugated system , nickel , chemistry , enyne , combinatorial chemistry , lewis acids and bases , molecule , polymer chemistry , medicinal chemistry , organic chemistry , polymer

Adding across : A C(sp)C(sp) bond of alkynyl cyanides is activated by nickel/Lewis acid catalysis derived from [Ni(cod) 2 ] and BPh 3 , and the alkynylcyanation reaction of alkynes and 1,2‐dienes is achieved by the binary catalysis for the first time to give a range of functionalized conjugated enyne molecules with defined stereo‐ and regioselectivities.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research