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A Zirconium Hydrazide as a Synthon for a Metallanitrene Equivalent: Atom‐by‐Atom Assembly of [EN 2 ] 2− Units (E=S, Se) by Chalcogen‐Atom Transfer in the Coordination Sphere of a Transition Metal
Author(s) -
Herrmann Heike,
Lloret Fillol Julio,
Wadepohl Hubert,
Gade Lutz H.
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200703938
Subject(s) - synthon , chalcogen , atom (system on chip) , chemistry , bridging (networking) , zirconium , crystallography , stereochemistry , computer science , organic chemistry , operating system , computer network
Piece by piece : Hydrazides at zirconium centers undergo facile NN bond cleavage and react as equivalents for metallanitrenes, thus allowing the atom‐by‐atom assembly of bridging dinitridosulfate(IV) and dinitridoselenate(IV) ligands (see scheme; TBS= t BuMe 2 Si).