A Zirconium Hydrazide as a Synthon for a Metallanitrene Equivalent: Atom‐by‐Atom Assembly of [EN 2 ] 2−  Units (E=S, Se) by Chalcogen‐Atom Transfer in the Coordination Sphere of a Transition Metal | Zendy

Herrmann Heike | Zendy; Lloret Fillol Julio | Zendy; Wadepohl Hubert | Zendy; Gade Lutz H. | Zendy

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A Zirconium Hydrazide as a Synthon for a Metallanitrene Equivalent: Atom‐by‐Atom Assembly of [EN 2 ] 2− Units (E=S, Se) by Chalcogen‐Atom Transfer in the Coordination Sphere of a Transition Metal

Author(s) -

Herrmann Heike,

Lloret Fillol Julio,

Wadepohl Hubert,

Gade Lutz H.

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200703938

Subject(s) - synthon , chalcogen , atom (system on chip) , chemistry , bridging (networking) , zirconium , crystallography , stereochemistry , computer science , organic chemistry , operating system , computer network

Piece by piece : Hydrazides at zirconium centers undergo facile NN bond cleavage and react as equivalents for metallanitrenes, thus allowing the atom‐by‐atom assembly of bridging dinitridosulfate(IV) and dinitridoselenate(IV) ligands (see scheme; TBS= t BuMe 2 Si).

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