Star‐Burst Prisms with Cyclotriveratrylene‐Type Ligands: A [Pd 6 L 8 ] 12+  Stella Octangular Structure | Zendy

Ronson Tanya K. | Zendy; Fisher Julie | Zendy; Harding Lindsay P. | Zendy; Hardie Michaele J. | Zendy

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Star‐Burst Prisms with Cyclotriveratrylene‐Type Ligands: A [Pd 6 L 8 ] 12+ Stella Octangular Structure

Author(s) -

Ronson Tanya K.,

Fisher Julie,

Harding Lindsay P.,

Hardie Michaele J.

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200703903

Subject(s) - stella (programming language) , supramolecular chemistry , radius , crystallography , star (game theory) , chemistry , molecule , type (biology) , stereochemistry , physics , crystal structure , astrophysics , organic chemistry , ecology , computer security , biology , computer science , thermodynamics

Star treatment : Host molecule tris(isonicotinoyl)cyclotriguaiacylene self‐assembles with Pd(NO 3 ) 2 to form a [Pd 6 L 8 ] 12+ metallo‐supramolecular cage of over 3 nm in diameter that resembles a stella octangular structure (see picture). ESMS and DOSY NMR studies show the assembly also exists in solution with a hydrodynamic radius of approximately 19 Å.

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