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Li 6 PS 5 X: A Class of Crystalline Li‐Rich Solids With an Unusually High Li + Mobility
Author(s) -
Deiseroth HansJörg,
Kong ShiaoTong,
Eckert Hellmut,
Vannahme Julia,
Reiner Christof,
Zaiß Torsten,
Schlosser Marc
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200703900
Subject(s) - halide , lithium (medication) , ion , crystallography , metal , crystal (programming language) , electron mobility , materials science , range (aeronautics) , chemistry , inorganic chemistry , analytical chemistry (journal) , optoelectronics , organic chemistry , metallurgy , medicine , computer science , composite material , programming language , endocrinology
Mobile metal ions : Halide‐substituted lithium argyrodites form a new class of Li‐rich solids with an unusually high Li mobility. Single‐crystal X‐ray studies (see picture; Li black, S yellow, I red) at room temperature and MAS‐NMR measurements in a wide temperature range provide insights into the Li + ion dynamics.