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Chiral Recognition with Silicon‐Stereogenic Silanes: Remarkable Selectivity Factors in the Kinetic Resolution of Donor‐Functionalized Alcohols
Author(s) -
Klare Hendrik F. T.,
Oestreich Martin
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200703847
Subject(s) - silanes , selectivity , stereocenter , silicon , silane , chirality (physics) , enantiomer , kinetic resolution , rhodium , substrate (aquarium) , chemistry , enantioselective synthesis , materials science , combinatorial chemistry , organic chemistry , catalysis , chiral symmetry , physics , oceanography , quantum mechanics , quark , geology , nambu–jona lasinio model
Slick silicon : A low‐molecular‐weight silane (C 13 H 20 Si, 204.38 g mol −1 ) with silicon‐centered chirality is capable of discriminating enantiomeric rhodium–substrate complexes in dehydrogenative SiO coupling reactions with outstanding selectivity factors (see scheme, s =selectivity factor).