Chiral Recognition with Silicon‐Stereogenic Silanes: Remarkable Selectivity Factors in the Kinetic Resolution of Donor‐Functionalized Alcohols | Zendy

Klare Hendrik F. T. | Zendy; Oestreich Martin | Zendy

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Chiral Recognition with Silicon‐Stereogenic Silanes: Remarkable Selectivity Factors in the Kinetic Resolution of Donor‐Functionalized Alcohols

Author(s) -

Klare Hendrik F. T.,

Oestreich Martin

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200703847

Subject(s) - silanes , selectivity , stereocenter , silicon , silane , chirality (physics) , enantiomer , kinetic resolution , rhodium , substrate (aquarium) , chemistry , enantioselective synthesis , materials science , combinatorial chemistry , organic chemistry , catalysis , chiral symmetry , physics , oceanography , quantum mechanics , quark , geology , nambu–jona lasinio model

Slick silicon : A low‐molecular‐weight silane (C 13 H 20 Si, 204.38 g mol −1 ) with silicon‐centered chirality is capable of discriminating enantiomeric rhodium–substrate complexes in dehydrogenative SiO coupling reactions with outstanding selectivity factors (see scheme, s =selectivity factor).

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