Reassignment of the Structure of the Antibiotic A53868 Reveals an Unusual Amino Dehydrophosphonic Acid | Zendy

Whitteck John T. | Zendy; Ni Weijuan | Zendy; Griffin Benjamin M. | Zendy; Eliot Andrew C. | Zendy; Thomas Paul M. | Zendy; Kelleher Neil L. | Zendy; Metcalf William W. | Zendy; van der Donk Wilfred A. | Zendy

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Reassignment of the Structure of the Antibiotic A53868 Reveals an Unusual Amino Dehydrophosphonic Acid

Author(s) -

Whitteck John T.,

Ni Weijuan,

Griffin Benjamin M.,

Eliot Andrew C.,

Thomas Paul M.,

Kelleher Neil L.,

Metcalf William W.,

van der Donk Wilfred A.

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200703810

Subject(s) - phosphonate , antibiotics , chemistry , charm (quantum number) , content (measure theory) , stereochemistry , combinatorial chemistry , organic chemistry , biochemistry , physics , mathematics , mathematical analysis , quantum mechanics

Third time's the charm! The structure of the phosphonate antibiotic A53868, first isolated in 1983 from Streptomyces luridus , has proven quite elusive. Originally reported as 1 and later revised to 2 , the actual structure of the compound is the unusual dehydro aminophosphonic acid 3 .

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