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Superhyperfine Interaction in [MnF 6 ] 3−
Author(s) -
Scheifele Quirin,
Birk Torben,
Bendix Jesper,
TregennaPiggott Philip L. W.,
Weihe Høgni
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200703771
Subject(s) - electron paramagnetic resonance , manganese , chemistry , ion , spectrum (functional analysis) , jahn–teller effect , electronic structure , nuclear magnetic resonance , distortion (music) , crystallography , materials science , physics , computational chemistry , optoelectronics , amplifier , organic chemistry , cmos , quantum mechanics
Resolved at last : A conventional spectrometer afforded the first EPR spectrum of a manganese(III) complex, namely [MnF 6 ] 3− , featuring clearly resoved superhyperfine interactions. It is shown how the nature of the Jahn–Teller distortion and the concomitant electronic structure (see picture) can be deduced from a single EPR spectrum and how the electronic structure of the central ion is reflected in the superhyperfine interaction with the surrounding ligands.