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Synthesis and Characterization of the Gold(I) Tris(ethylene) Complex [Au(C 2 H 4 ) 3 ][SbF 6 ]
Author(s) -
Dias H. V. Rasika,
Fianchini Mauro,
Cundari Thomas R.,
Campana Charles F.
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200703515
Subject(s) - ethylene , tris , characterization (materials science) , salt (chemistry) , content (measure theory) , molecule , chemistry , crystallography , stereochemistry , combinatorial chemistry , materials science , nanotechnology , organic chemistry , catalysis , mathematics , biochemistry , mathematical analysis
Ethylene el dorado : Gold(I) unusually takes up three ethylene molecules in a spoked‐wheel arrangement (see picture). The complex was synthesized as the hexafluoroantimonate salt and structurally characterized.