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Oxidant‐Free Alcohol Dehydrogenation Using a Reusable Hydrotalcite‐Supported Silver Nanoparticle Catalyst
Author(s) -
Mitsudome Takato,
Mikami Yusuke,
Funai Hisashi,
Mizugaki Tomoo,
Jitsukawa Koichiro,
Kaneda Kiyotomi
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200703161
Subject(s) - dehydrogenation , hydrotalcite , catalysis , hydrogen peroxide , chemistry , alcohol oxidation , alcohol , selectivity , nanoparticle , heterogeneous catalysis , organic chemistry , combinatorial chemistry , nanotechnology , materials science
Additive free : Hydrotalcite‐supported silver nanoparticles act as a highly efficient heterogeneous catalyst for the dehydrogenation of diverse alcohols (see picture) in the absence of any acceptors such as molecular oxygen, hydrogen peroxide, or unsaturated organic compounds. The solid Ag catalyst was readily reusable without any loss of activity and selectivity.