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Synthesis and Structure of a Hydrido(hydrosilylene)ruthenium Complex and Its Reactions with Nitriles
Author(s) -
Ochiai Mitsuyoshi,
Hashimoto Hisako,
Tobita Hiromi
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200703154
Subject(s) - agostic interaction , silylene , chemistry , pyridine , ruthenium , ring (chemistry) , ligand (biochemistry) , medicinal chemistry , catalysis , metal , organic chemistry , silicon , biochemistry , receptor
Ring around the RuSi : Abstraction of a pyridine ligand with BPh 3 was used to synthesize the silylene complex 1 (see scheme), which reacts with nitriles at room temperature to give silylisocyanide complex 3 by CC bond activation. The structure of key intermediate 2 with an η 2 ‐SiH agostic interaction is given along with mechanisms for the formation of 2 and 3 .
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