Facile Incorporation of Platinum(IV) into Polyoxometalate Frameworks: Preparation of [H 2 Pt IV V 9 O 28 ] 5−  and Characterization by  195 Pt NMR Spectroscopy | Zendy

Lee Uk | Zendy; Joo HeaChung | Zendy; Park KiMin | Zendy; Mal Sib Sankar | Zendy; Kortz Ulrich | Zendy; Keita Bineta | Zendy; Nadjo Louis | Zendy

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Facile Incorporation of Platinum(IV) into Polyoxometalate Frameworks: Preparation of [H 2 Pt IV V 9 O 28 ] 5− and Characterization by 195 Pt NMR Spectroscopy

Author(s) -

Lee Uk,

Joo HeaChung,

Park KiMin,

Mal Sib Sankar,

Kortz Ulrich,

Keita Bineta,

Nadjo Louis

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200703082

Subject(s) - polyoxometalate , platinum , vanadate , characterization (materials science) , chemistry , spectroscopy , nuclear magnetic resonance spectroscopy , crystallography , nanotechnology , stereochemistry , inorganic chemistry , materials science , physics , catalysis , organic chemistry , quantum mechanics

A new mate for vanadate : The platinum(IV)‐containing polyoxovanadate [H 2 Pt IV V 9 O 28 ] 5− ( 1 ) has been synthesized and structurally characterized (see polyhedral representation). The characterization of polyanion 1 in solution by 195 Pt NMR spectroscopy is unprecedented in POM chemistry. The facile synthetic procedure with the Pt IV precursor H 2 Pt(OH) 6 appears to be a convenient and general methodology for making a large variety of Pt IV ‐containing polyoxometalates.

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