[Rh 7 (P i Pr 3 ) 6 H 18 ][BAr F  4 ] 2 : A Molecular Rh(111) Surface Decorated with 18 Hydrogen Atoms | Zendy

Brayshaw Simon K. | Zendy; Green Jennifer C. | Zendy; Edge Ruth | Zendy; McInnes Eric J. L. | Zendy; Raithby Paul R. | Zendy; Warren John E. | Zendy; Weller Andrew S. | Zendy

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[Rh 7 (P i Pr 3 ) 6 H 18 ][BAr F 4 ] 2 : A Molecular Rh(111) Surface Decorated with 18 Hydrogen Atoms

Author(s) -

Brayshaw Simon K.,

Green Jennifer C.,

Edge Ruth,

McInnes Eric J. L.,

Raithby Paul R.,

Warren John E.,

Weller Andrew S.

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200703069

Subject(s) - norbornadiene , hydride , crystallography , physics , bar (unit) , chemistry , hydrogen , stereochemistry , catalysis , biochemistry , quantum mechanics , meteorology

Heptarhodium wagon wheel [Rh 7 (P i Pr 3 ) 6 H 18 ][BAr F 4 ] 2 (shown), which resembles a planar Rh(111) surface with 18 hydride ligands, was obtained together with [Rh 8 (P i Pr 3 ) 6 H 16 ][BAr F 4 ] 2 from the reaction of [Rh(P i Pr 3 ) 2 (nbd)][BAr F 4 ] and [Rh(nbd) 2 ][BAr F 4 ] with hydrogen (Ar F =C 6 H 3 (CF 3 ) 2 , nbd=norbornadiene). Some of the H ligands are located in threefold hollows between Rh centers and thus mimic the orientation of atomic hydrogen adsorbed on Rh(111).

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