Self‐Organization of Electroactive Materials: A Head‐to‐Tail Donor–Acceptor Supramolecular Polymer | Zendy

Fernández Gustavo | Zendy; Pérez Emilio M. | Zendy; Sánchez Luis | Zendy; Martín Nazario | Zendy

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Self‐Organization of Electroactive Materials: A Head‐to‐Tail Donor–Acceptor Supramolecular Polymer

Author(s) -

Fernández Gustavo,

Pérez Emilio M.,

Sánchez Luis,

Martín Nazario

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200703049

Subject(s) - supramolecular chemistry , monomer , fullerene , polymer , supramolecular polymers , polymer science , head (geology) , acceptor , linear polymer , nanotechnology , chemistry , polymer chemistry , materials science , organic chemistry , physics , molecule , condensed matter physics , geomorphology , geology

Fullerenes do the conga! Synthesis and self‐recognition of a monomer featuring a specially designed receptor for [60]fullerene are described. The monomer self‐assembles in a head‐to‐tail fashion through π–π interactions, thus forming a linear oligomeric species in solution (see image). The formation of this redox‐amphoteric supramolecular polymer represents a new approach to the controlled organization of electroactive materials.

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