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A Cheap, Efficient, and Environmentally Benign Synthesis of the Versatile Catalyst Methyltrioxorhenium (MTO)
Author(s) -
Herrmann Wolfgang A.,
Rost Alexandra M. J.,
Mitterpleininger Josef K. M.,
Szesni Normen,
Sturm Stefanie,
Fischer Richard W.,
Kühn Fritz E.
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200703017
Subject(s) - catalysis , yield (engineering) , environmentally friendly , chemistry , organic chemistry , chemical engineering , materials science , engineering , metallurgy , ecology , biology
Avoiding toxic starting materials such as (CH 3 ) 4 Sn, a cheap, environmentally benign high‐yield synthesis has been developed for the multitalented catalyst methyltrioxorhenium(VII) (MTO; see picture: black C, white H, blue Re, red O). This novel approach is applicable on a large scale and for several derivatives of MTO, such as ethyltrioxorhenium(VII).
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