Regio‐ and Enantioselective Direct Oxyamination Reaction of Aldehydes Catalyzed by α,α‐Diphenylprolinol Trimethylsilyl Ether | Zendy

Palomo Claudio | Zendy; Vera Silvia | Zendy; Velilla Irene | Zendy; Mielgo Antonia | Zendy; GómezBengoa Enrique | Zendy

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Regio‐ and Enantioselective Direct Oxyamination Reaction of Aldehydes Catalyzed by α,α‐Diphenylprolinol Trimethylsilyl Ether

Author(s) -

Palomo Claudio,

Vera Silvia,

Velilla Irene,

Mielgo Antonia,

GómezBengoa Enrique

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200703001

Subject(s) - enantioselective synthesis , chemistry , nitrosobenzene , catalysis , trimethylsilyl , ether , organic chemistry

Donors not required : External hydrogen‐bond donors are not required for a highly regio‐ and enantioselective oxyamination reaction of aldehydes with nitrosobenzene (see scheme). The reaction proceeds in the presence of the structurally simple organocatalyst (−)‐( S )‐α,α‐diphenylprolinol trimethylsilyl ether to afford the oxyaminated compounds in good yields.

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