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A Concave‐Bound CpFe Complex of Sumanene as a Metal in a π Bowl
Author(s) -
Amaya Toru,
Sakane Hiroyuki,
Hirao Toshikazu
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200702826
Subject(s) - ferrocene , cyclopentadienyl complex , fragment (logic) , ligand (biochemistry) , terminal (telecommunication) , ring (chemistry) , metal , chemistry , stereochemistry , computer science , organic chemistry , catalysis , telecommunications , algorithm , biochemistry , receptor , electrode , electrochemistry
Dished up : The selective synthesis of a concave‐bound iron complex was achieved by ligand exchange of a cyclopentadienyl ring of ferrocene with a fullerene‐fragment π bowl, sumanene (see picture). The concave π surface serves as an η 6 ligand.