Observation of Three Intervalence‐Transfer Bands for a Class II–III Mixed‐Valence Complex of Ruthenium | Zendy

Rocha Reginaldo C. | Zendy; Rein Francisca N. | Zendy; Jude Hershel | Zendy; Shreve Andrew P. | Zendy; Concepcion Javier J. | Zendy; Meyer Thomas J. | Zendy

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Observation of Three Intervalence‐Transfer Bands for a Class II–III Mixed‐Valence Complex of Ruthenium

Author(s) -

Rocha Reginaldo C.,

Rein Francisca N.,

Jude Hershel,

Shreve Andrew P.,

Concepcion Javier J.,

Meyer Thomas J.

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200702760

Subject(s) - delocalized electron , valence (chemistry) , crystallography , chemistry , class (philosophy) , ruthenium , valence band , pyrazine , spectral line , physics , computer science , stereochemistry , condensed matter physics , quantum mechanics , band gap , artificial intelligence , organic chemistry , catalysis , biochemistry

Multiple intervalence‐transfer (IT) absorptions (see picture) appear in the near‐IR/IR spectra of the mixed‐valence complex [Cl 3 Ru II (tppz)Ru III Cl 3 ] − (tppz=tetrakis(2‐pyridyl)pyrazine), whose X‐ray crystal structure and electronic and vibrational spectroscopic features indicate localized‐to‐delocalized (Class II–III) behavior.

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