Premium
Modular Assembly of a Functional Polyoxometalate‐Based Open Framework Constructed from Unsupported Ag I ⋅⋅⋅Ag I Interactions
Author(s) -
Streb Carsten,
Ritchie Chris,
Long DeLiang,
Kögerler Paul,
Cronin Leroy
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200702698
No ligand support : Modular assembly of the title system (see picture; Ag purple, W blue, O red) has been achieved using {H 3 W 12 O 40 } 5− and {Ag 2 } 2+ building blocks to give a material with [Ag(CH 3 CN) 4 ] + ions in its microporous channels. This framework is constructed by unsupported Ag I ⋅⋅⋅Ag I interactions, and sorption studies show that the framework can reversibly adsorb up to 10 wt % acetonitrile.