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Homoleptic Silver(I) Acetylene Complexes
Author(s) -
Reisinger Andreas,
Trapp Nils,
Krossing Ingo,
Altmannshofer Sandra,
Herz Verena,
Presnitz Manuel,
Scherer Wolfgang
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200702688
Subject(s) - homoleptic , acetylene , metal , chemistry , solid state , crystallography , materials science , inorganic chemistry , organic chemistry
Hanging on to acetylene : The solid‐state structures of the first homoleptic metal HCCH complexes [M(C 2 H 2 ) x ] n (M=any metal; n, x =any number), salts of [Ag(η 2 ‐C 2 H 2 ) n ] + ( n =3,4), are described (see picture). The electronic structure of a [Ag(η 2 ‐C 2 H 2 )] model complex has been investigated by experimental charge‐density studies.