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Synthesis of Pentafluorosulfanyl Trifluorovinyl Ether and Its Facile Rearrangement to Difluoro(pentafluorosulfanyl)acetyl Fluoride
Author(s) -
Du Libin,
Elliott Bevan,
Echegoyen Luis,
DesMarteau Darryl D.
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200702425
Subject(s) - chemistry , fluoride , ether , environmental chemistry , organic chemistry , inorganic chemistry
A radical departure : A novel fluorinated vinyl ether 1 was synthesized and was found to undergo an unexpected facile rearrangement to give compound 2 , which was confirmed to be a radical process by EPR spectroscopy.
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